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Two novel metal–organic frameworks functionalised with pentamethylcyclopentadienyl iridium(iii) chloride for catalytic conversion of carbon dioxide to formate†

Two novel metal–organic frameworks functionalised with pentamethylcyclopentadienyl iridium(iii) chloride for catalytic conversion of carbon dioxide to formate†

Hydrogenation of CO2 to formate is a vital reaction, because formate is an excellent hydrogen carrier, which yields blue hydrogen. Blue hydrogen is comparatively cheaper and attractive as the world envisions the hydrogen economy. In this work, two isostructural lanthanide-based MOFs (JMS-6 and JMS-7...

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Bibliographic Details
Main Authors: Maureen Gumbo, Banothile C. E. Makhubela, Gift Mehlana
Other Authors: Department of Chemical Sciences, Faculty of Science and Technology, Midlands State University, Private Bag 9055, Senga Road, Gweru, Zimbabwe; Research Centre for Synthesis and Catalysis, Department of Chemical Sciences, University of Johannesburg, Auckland Park, Kingsway Campus, South Africa
Format: research article
Language:English
Published: Royal Society of Chemistry 2023
Subjects:
Novel metal–organic frameworks
Pentamethylcyclopentadienyl iridium(iii) chloride
Catalytic conversion
Carbon dioxide
formate†
Online Access:https://cris.library.msu.ac.zw//handle/11408/5648
https://doi.org/10.1039/D3DT00635B
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https://cris.library.msu.ac.zw//handle/11408/5648
https://doi.org/10.1039/D3DT00635B