Mechanisms of electrocatalysis of oxygen reduction by metal porphyrins in trifluorom ethane sulfonic acid solution

This study examines the oxygen reduction reaction (ORR) in a homogeneous catalyst system, comparing between the outer-sphere and inner-sphere electron-transfer mechanisms. The rate constants are measured using aqueous trifluoromethane sulfonic acid (TFMSA) and water-soluble M*meso-tetra(pyridyl)porp...

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Bibliographic Details
Main Authors: He, Qinggang, Mugadza, Tawanda, Hwang, GiSuk, Nyokong, Tebello
Format: Article
Language:English
Published: Electrochemical Science Group 2016
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Online Access:http://www.electrochemsci.org/papers/vol7/7087045.pdf
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