Skip recommendations
Skip recommendations
-
1by Johannes Hungwe, Piwai Tshuma, Maureen Gumbo, Francoise M. Amombo Noa, Lars Öhrström, Gift Mehlana“…By introducing a modulator, 1,10-phenanthroline, the 3D network [La(bpda)3/2(dmf)(H2O)2]·dmf MSU-11 could be isolated with the unusual rod-MOF topology zbj. Both the 2D and 3D networks are stable upon guest removal and the activated phases of MSU-10 and MSU-11 exhibit some phase change when soaked in solvents for 24 h. …”
Published 2023
Get full text
Get full text
research article -
2
-
3“…The solvothermal reaction of 3-(4-pyridyl)benzoic acid and zinc nitrate yielded a 2D network with an sql topology. Both elemental analysis and single crystal X-ray diffraction studies confirmed the formula of the compound as {[Zn(34pba)2] · (0.5 DMF) · (0.5 H2O)}n (1). …”
Get full text
Get full text
Get full text
Article -
4“…Two coordination networks, {[Co(34pba)2]·DMF}n (1 and 2), where 34pba is 3-(4-pyridyl)benzoate, were prepared by solvothermal methods. 1 is a three-dimensional metal organic framework formed by linking [Co2(34pba)8] clusters in a bcu net. 2 consists of single [Co(34pba)4] units in a tetragonal plane net of sql topology. The thermal conditions leading to their selective synthesis were established: 120 °C for 1 and 75 °C for 2. …”
Get full text
Get full text
Article -
5Cyclometalation of lanthanum(III) based MOF for catalytic hydrogenation of carbon dioxide to formateby Tshuma, Piwai, Makhubela, Banothile C. E., Ohrstr ¨ om, Lars, Bourne, Susan A., Chatterjee, Nabanita, Beas, Isaac N., Darkwa, James, Mehlana, Gift“…Network analysis of JMS-1 revealed a new 7-connected topology (zaz). The MOF backbone of the activated phase (JMS-1a) was functionalized by cyclometalation using [RuCl2(p-cymene)]2 to produce Ru(II)@JMS-1a. …”
Published 2021
Get full text
Get full text
Article -
6by Mehlana, Gift“…Structural elucidation of compounds was performed by single crystal X-ray diffraction. Topological analysis was performed on the networks formed by the compounds to have a better understanding of the network connectivity. …”
Published 2017
Get full text
Get full text