Extraction of water treatment coagulant from locally abundant kaolin clays

Rapid industrialisation is contributing to water pollution. There is a need to identify cheaper and efficient methods of removing contaminants as the demand for clean water rises. A study is carried out to investigate the extraction of alum from locally abundant kaolin clays using sulphuric acid. Al...

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Main Authors: Chigondo, Fidelis, Nyamunda, Benias Chomunorwa, Bhebhe, Vuyo
Format: Article
Language:English
Published: Hindawi 2021
Subjects:
Online Access:https://doi.org/10.1155/2015/705837
https://www.hindawi.com/journals/jchem/2015/705837/
http://hdl.handle.net/11408/4415
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author Chigondo, Fidelis
Nyamunda, Benias Chomunorwa
Bhebhe, Vuyo
author_facet Chigondo, Fidelis
Nyamunda, Benias Chomunorwa
Bhebhe, Vuyo
author_sort Chigondo, Fidelis
collection DSpace
description Rapid industrialisation is contributing to water pollution. There is a need to identify cheaper and efficient methods of removing contaminants as the demand for clean water rises. A study is carried out to investigate the extraction of alum from locally abundant kaolin clays using sulphuric acid. Alum is a coagulant that is used for raw water treatment. The kaolin clay and alum were characterized by Fourier transformation infrared spectroscopy (FTIR). The effects of particle size, calcination temperature, calcination time, acid-kaolin clay ratio, acid concentration, leaching temperature, and leaching time on extraction efficiency were investigated. The optimum leaching conditions for the calcined kaolin clay were found to be particle size 100 µm, acid-kaolin clay weight ratio 6 : 1, acid concentration 4 M, leaching temperature 100°C, and leaching time 90 min. Under optimised conditions, 66.95% (w/w) aluminum sulphate was extracted. The results showed that sulphuric acid could be used on a large scale to extract alum from kaolin clay. The extracted alum showed similar structural and physical characteristics compared with commercial alum. A dosage of 40 mg/L of the extracted alum showed effective coagulant properties with a great potential of treating raw water.
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spelling ir-11408-44152022-06-27T13:49:06Z Extraction of water treatment coagulant from locally abundant kaolin clays Chigondo, Fidelis Nyamunda, Benias Chomunorwa Bhebhe, Vuyo Rapid industrialisation Rapid industrialisation is contributing to water pollution. There is a need to identify cheaper and efficient methods of removing contaminants as the demand for clean water rises. A study is carried out to investigate the extraction of alum from locally abundant kaolin clays using sulphuric acid. Alum is a coagulant that is used for raw water treatment. The kaolin clay and alum were characterized by Fourier transformation infrared spectroscopy (FTIR). The effects of particle size, calcination temperature, calcination time, acid-kaolin clay ratio, acid concentration, leaching temperature, and leaching time on extraction efficiency were investigated. The optimum leaching conditions for the calcined kaolin clay were found to be particle size 100 µm, acid-kaolin clay weight ratio 6 : 1, acid concentration 4 M, leaching temperature 100°C, and leaching time 90 min. Under optimised conditions, 66.95% (w/w) aluminum sulphate was extracted. The results showed that sulphuric acid could be used on a large scale to extract alum from kaolin clay. The extracted alum showed similar structural and physical characteristics compared with commercial alum. A dosage of 40 mg/L of the extracted alum showed effective coagulant properties with a great potential of treating raw water. 2021-06-08T12:17:37Z 2021-06-08T12:17:37Z 2015 Article 2090-9063 2090-9071 https://doi.org/10.1155/2015/705837 https://www.hindawi.com/journals/jchem/2015/705837/ http://hdl.handle.net/11408/4415 en Journal of Chemistry;Special Issue: Water: Analysis, Treatment, and Reuse open Hindawi
spellingShingle Rapid industrialisation
Chigondo, Fidelis
Nyamunda, Benias Chomunorwa
Bhebhe, Vuyo
Extraction of water treatment coagulant from locally abundant kaolin clays
title Extraction of water treatment coagulant from locally abundant kaolin clays
title_full Extraction of water treatment coagulant from locally abundant kaolin clays
title_fullStr Extraction of water treatment coagulant from locally abundant kaolin clays
title_full_unstemmed Extraction of water treatment coagulant from locally abundant kaolin clays
title_short Extraction of water treatment coagulant from locally abundant kaolin clays
title_sort extraction of water treatment coagulant from locally abundant kaolin clays
topic Rapid industrialisation
url https://doi.org/10.1155/2015/705837
https://www.hindawi.com/journals/jchem/2015/705837/
http://hdl.handle.net/11408/4415
work_keys_str_mv AT chigondofidelis extractionofwatertreatmentcoagulantfromlocallyabundantkaolinclays
AT nyamundabeniaschomunorwa extractionofwatertreatmentcoagulantfromlocallyabundantkaolinclays
AT bhebhevuyo extractionofwatertreatmentcoagulantfromlocallyabundantkaolinclays