“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide

Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene...

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Main Authors: Shumba, Munyaradzi, Mashazi, Philani, Nyokong, Tebello
Format: Article
Language:English
Published: Elsevier 2018
Subjects:
Online Access:https://www.infona.pl/resource/bwmeta1.element.elsevier-3bd70787-4885-342e-8b4a-40b93149db70
http://hdl.handle.net/11408/3296
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author Shumba, Munyaradzi
Mashazi, Philani
Nyokong, Tebello
author_facet Shumba, Munyaradzi
Mashazi, Philani
Nyokong, Tebello
author_sort Shumba, Munyaradzi
collection DSpace
description Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
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spelling ir-11408-32962022-06-27T13:49:06Z “Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide Shumba, Munyaradzi Mashazi, Philani Nyokong, Tebello Reduced graphene oxide nanosheets Photoinduced electron transfer Fluorescence enhancement Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences. 2018-11-02T08:39:14Z 2018-11-02T08:39:14Z 2016 Article 0022-2313 https://www.infona.pl/resource/bwmeta1.element.elsevier-3bd70787-4885-342e-8b4a-40b93149db70 http://hdl.handle.net/11408/3296 en Journal of Luminescence;Vol. 170: p. 317-324 open Elsevier
spellingShingle Reduced graphene oxide nanosheets
Photoinduced electron transfer
Fluorescence enhancement
Shumba, Munyaradzi
Mashazi, Philani
Nyokong, Tebello
“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
title “Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
title_full “Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
title_fullStr “Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
title_full_unstemmed “Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
title_short “Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
title_sort “turn on” fluorescence enhancement of zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
topic Reduced graphene oxide nanosheets
Photoinduced electron transfer
Fluorescence enhancement
url https://www.infona.pl/resource/bwmeta1.element.elsevier-3bd70787-4885-342e-8b4a-40b93149db70
http://hdl.handle.net/11408/3296
work_keys_str_mv AT shumbamunyaradzi turnonfluorescenceenhancementofznoctacarboxyphthaloyaninegrapheneoxideconjugatesbyhydrogenperoxide
AT mashaziphilani turnonfluorescenceenhancementofznoctacarboxyphthaloyaninegrapheneoxideconjugatesbyhydrogenperoxide
AT nyokongtebello turnonfluorescenceenhancementofznoctacarboxyphthaloyaninegrapheneoxideconjugatesbyhydrogenperoxide