Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands
Two py-functionalized perylene bisimide ligands were synthesized and used to make bimetallic half-sandwich Ru(II) complexes. These were characterized by IR, 1H NMR, 13C CPMAS SSNMR spectroscopy, and elemental analysis. The complexes are wheel-and-axle (waa) compounds, where the axle is the divergent...
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Taylor & Francis
2016
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| Online Access: | http://dx.doi.org/10.1080/15533174.2016.1186068 http://hdl.handle.net/11408/1866 |
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| author | Pagano, Paolo Pelagatti, Paolo Bacchi, Alessia Chierotti, Michele R. Bourne, Susan A. Mehlana, Gift |
| author_facet | Pagano, Paolo Pelagatti, Paolo Bacchi, Alessia Chierotti, Michele R. Bourne, Susan A. Mehlana, Gift |
| author_sort | Pagano, Paolo |
| collection | DSpace |
| description | Two py-functionalized perylene bisimide ligands were synthesized and used to make bimetallic half-sandwich Ru(II) complexes. These were characterized by IR, 1H NMR, 13C CPMAS SSNMR spectroscopy, and elemental analysis. The complexes are wheel-and-axle (waa) compounds, where the axle is the divergent ligand and the wheels are the [(p-cymene)RuCl2] units. The complexes, but not the free ligands, showed absorption of volatile organic compounds such as toluene and xylenes through heterogeneous solid/gas uptakes. The reactivity is ascribable to the waa geometry, likely by an upset of the high stacking characterizing the crystalline frameworks of the free ligands. The kinetic profiles of the uptake reactions were determined. |
| format | Article |
| id | ir-11408-1866 |
| institution | My University |
| language | English |
| publishDate | 2016 |
| publisher | Taylor & Francis |
| record_format | dspace |
| spelling | ir-11408-18662022-06-27T13:49:06Z Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands Pagano, Paolo Pelagatti, Paolo Bacchi, Alessia Chierotti, Michele R. Bourne, Susan A. Mehlana, Gift Sorption Properties Two py-functionalized perylene bisimide ligands were synthesized and used to make bimetallic half-sandwich Ru(II) complexes. These were characterized by IR, 1H NMR, 13C CPMAS SSNMR spectroscopy, and elemental analysis. The complexes are wheel-and-axle (waa) compounds, where the axle is the divergent ligand and the wheels are the [(p-cymene)RuCl2] units. The complexes, but not the free ligands, showed absorption of volatile organic compounds such as toluene and xylenes through heterogeneous solid/gas uptakes. The reactivity is ascribable to the waa geometry, likely by an upset of the high stacking characterizing the crystalline frameworks of the free ligands. The kinetic profiles of the uptake reactions were determined. 2016-11-28T14:32:49Z 2016-11-28T14:32:49Z 2016 Article 1553-3174 http://dx.doi.org/10.1080/15533174.2016.1186068 http://hdl.handle.net/11408/1866 en Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry;Vol. 47, No. 3; p. 427-432 open Taylor & Francis |
| spellingShingle | Sorption Properties Pagano, Paolo Pelagatti, Paolo Bacchi, Alessia Chierotti, Michele R. Bourne, Susan A. Mehlana, Gift Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands |
| title | Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands |
| title_full | Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands |
| title_fullStr | Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands |
| title_full_unstemmed | Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands |
| title_short | Sorption properties towards environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene-bis-imide ligands |
| title_sort | sorption properties towards environmentally important vocs of half-sandwich ru(ii) complexes containing perylene-bis-imide ligands |
| topic | Sorption Properties |
| url | http://dx.doi.org/10.1080/15533174.2016.1186068 http://hdl.handle.net/11408/1866 |
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