Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis†
Two new metal–organic frameworks based on 2,2′-bipyridine-4,4′-dicarboxylate and La(III) ions were prepared under solvothermal conditions. [La(bpda)3/2(dmf)2]·dmf·H2O, MSU-10, was isolated as a 2D network structure. By introducing a modulator, 1,10-phenanthroline, the 3D network [La(bpda)3/2(dmf)(H2...
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| Language: | English |
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Royal Society of Chemistry
2023
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| Online Access: | https://cris.library.msu.ac.zw//handle/11408/5525 https://doi.org/10.1039/D3CE00039G |
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| author | Johannes Hungwe Piwai Tshuma Maureen Gumbo Francoise M. Amombo Noa Lars Öhrström Gift Mehlana |
| author2 | Midlands State University, Department of Chemical Sciences, 9055 Senga Road, Gweru, Zimbabwe |
| author_facet | Midlands State University, Department of Chemical Sciences, 9055 Senga Road, Gweru, Zimbabwe Johannes Hungwe Piwai Tshuma Maureen Gumbo Francoise M. Amombo Noa Lars Öhrström Gift Mehlana |
| author_sort | Johannes Hungwe |
| collection | DSpace |
| description | Two new metal–organic frameworks based on 2,2′-bipyridine-4,4′-dicarboxylate and La(III) ions were prepared under solvothermal conditions. [La(bpda)3/2(dmf)2]·dmf·H2O, MSU-10, was isolated as a 2D network structure. By introducing a modulator, 1,10-phenanthroline, the 3D network [La(bpda)3/2(dmf)(H2O)2]·dmf MSU-11 could be isolated with the unusual rod-MOF topology zbj. Both the 2D and 3D networks are stable upon guest removal and the activated phases of MSU-10 and MSU-11 exhibit some phase change when soaked in solvents for 24 h. Network analysis allowed the identification of MSU-11 as isoreticular with MOF-80 built from different linkers and metal ions. |
| format | research article |
| id | ir-11408-5525 |
| institution | My University |
| language | English |
| publishDate | 2023 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | ir-11408-55252023-04-05T07:21:21Z Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis† Johannes Hungwe Piwai Tshuma Maureen Gumbo Francoise M. Amombo Noa Lars Öhrström Gift Mehlana Midlands State University, Department of Chemical Sciences, 9055 Senga Road, Gweru, Zimbabwe Midlands State University, Department of Chemical Sciences, 9055 Senga Road, Gweru, Zimbabwe Midlands State University, Department of Chemical Sciences, 9055 Senga Road, Gweru, Zimbabwe Chalmers University of Technology, Department of Chemistry and Chemical Engineering, Physical Chemistry Room 9029, Göteborg, Sweden Chalmers University of Technology, Department of Chemistry and Chemical Engineering, Physical Chemistry Room 9029, Göteborg, Sweden Midlands State University, Department of Chemical Sciences, 9055 Senga Road, Gweru, Zimbabwe 2D metal–organic framework 2D to 3D Modulator assisted synthesis Two new metal–organic frameworks based on 2,2′-bipyridine-4,4′-dicarboxylate and La(III) ions were prepared under solvothermal conditions. [La(bpda)3/2(dmf)2]·dmf·H2O, MSU-10, was isolated as a 2D network structure. By introducing a modulator, 1,10-phenanthroline, the 3D network [La(bpda)3/2(dmf)(H2O)2]·dmf MSU-11 could be isolated with the unusual rod-MOF topology zbj. Both the 2D and 3D networks are stable upon guest removal and the activated phases of MSU-10 and MSU-11 exhibit some phase change when soaked in solvents for 24 h. Network analysis allowed the identification of MSU-11 as isoreticular with MOF-80 built from different linkers and metal ions. 10 1486 1494 2023-04-05T07:21:20Z 2023-04-05T07:21:20Z 2023-02-14 research article https://cris.library.msu.ac.zw//handle/11408/5525 https://doi.org/10.1039/D3CE00039G en CrystEngComm 1466-8033 open Royal Society of Chemistry |
| spellingShingle | 2D metal–organic framework 2D to 3D Modulator assisted synthesis Johannes Hungwe Piwai Tshuma Maureen Gumbo Francoise M. Amombo Noa Lars Öhrström Gift Mehlana Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis† |
| title | Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis† |
| title_full | Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis† |
| title_fullStr | Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis† |
| title_full_unstemmed | Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis† |
| title_short | Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis† |
| title_sort | tuning the topology of a 2d metal–organic framework from 2d to 3d using modulator assisted synthesis† |
| topic | 2D metal–organic framework 2D to 3D Modulator assisted synthesis |
| url | https://cris.library.msu.ac.zw//handle/11408/5525 https://doi.org/10.1039/D3CE00039G |
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