Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II)
In this study, we demonstrated a highly sensitive electrochemical sensor for the simultaneous detection of Pb (II) and Cd (II) in aqueous solution using carbon paste electrode modified with Eichhornia crassipes powder by square wave anodic stripping voltammetry. The effect of modifier composition, p...
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| Format: | Article |
| Language: | English |
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Taylor and Francis Ltd.
2021
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| Online Access: | https://www.tandfonline.com/doi/abs/10.1080/03067319.2018.1562061 http://hdl.handle.net/11408/4408 |
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| author | Jackfama, Tatenda Moyo, Mambo Nharingo, Tichaona Shumba, Munyaradzi Okonkwo, Jonathan |
| author_facet | Jackfama, Tatenda Moyo, Mambo Nharingo, Tichaona Shumba, Munyaradzi Okonkwo, Jonathan |
| author_sort | Jackfama, Tatenda |
| collection | DSpace |
| description | In this study, we demonstrated a highly sensitive electrochemical sensor for the simultaneous detection of Pb (II) and Cd (II) in aqueous solution using carbon paste electrode modified with Eichhornia crassipes powder by square wave anodic stripping voltammetry. The effect of modifier composition, pH, preconcentration time, reduction potential and time, and type of supporting electrolyte on the determination of metal ions were investigated. Pre-concentration on the modified surface was performed at open circuit. The modified electrode exhibited well-defined and separate stripping peaks for Pb (II) and Cd (II). Under optimum experimental conditions, a linear range for both metal ions was from 10 to 5000 μg L−1 with the detection limits of 4.9 μg L−1, 2.1 μg L−1 for Cd(II) and Pb (II), respectively. The modified electrode was found to be sensitive and selective when applied to determine trace amounts of Cd (II) and Pb (II) in natural water samples. |
| format | Article |
| id | ir-11408-4408 |
| institution | My University |
| language | English |
| publishDate | 2021 |
| publisher | Taylor and Francis Ltd. |
| record_format | dspace |
| spelling | ir-11408-44082022-06-27T13:49:06Z Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II) Jackfama, Tatenda Moyo, Mambo Nharingo, Tichaona Shumba, Munyaradzi Okonkwo, Jonathan Eichhornia Crassipes carbon paste electrode Cd (II) Pb (II) anodic stripping In this study, we demonstrated a highly sensitive electrochemical sensor for the simultaneous detection of Pb (II) and Cd (II) in aqueous solution using carbon paste electrode modified with Eichhornia crassipes powder by square wave anodic stripping voltammetry. The effect of modifier composition, pH, preconcentration time, reduction potential and time, and type of supporting electrolyte on the determination of metal ions were investigated. Pre-concentration on the modified surface was performed at open circuit. The modified electrode exhibited well-defined and separate stripping peaks for Pb (II) and Cd (II). Under optimum experimental conditions, a linear range for both metal ions was from 10 to 5000 μg L−1 with the detection limits of 4.9 μg L−1, 2.1 μg L−1 for Cd(II) and Pb (II), respectively. The modified electrode was found to be sensitive and selective when applied to determine trace amounts of Cd (II) and Pb (II) in natural water samples. 2021-06-08T12:01:09Z 2021-06-08T12:01:09Z 2019 Article 1029-0397 https://www.tandfonline.com/doi/abs/10.1080/03067319.2018.1562061 http://hdl.handle.net/11408/4408 en International Journal of Environmental Analytical Chemistry;Vol.99 ; Issue 1 : p.47-60 open Taylor and Francis Ltd. |
| spellingShingle | Eichhornia Crassipes carbon paste electrode Cd (II) Pb (II) anodic stripping Jackfama, Tatenda Moyo, Mambo Nharingo, Tichaona Shumba, Munyaradzi Okonkwo, Jonathan Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II) |
| title | Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II) |
| title_full | Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II) |
| title_fullStr | Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II) |
| title_full_unstemmed | Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II) |
| title_short | Water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of Cd (II) and Pb (II) |
| title_sort | water hyacinth modified carbon paste electrode for simultaneous electrochemical stripping analysis of cd (ii) and pb (ii) |
| topic | Eichhornia Crassipes carbon paste electrode Cd (II) Pb (II) anodic stripping |
| url | https://www.tandfonline.com/doi/abs/10.1080/03067319.2018.1562061 http://hdl.handle.net/11408/4408 |
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