Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen
The reaction of Cd(NO3)2·4H2O and Zn(NO3)2·6H2O with the bipyridyl dicarboxylate ligand H2bpydc (2,2′-bipyridine-4,4′-dicarboxylic acid) afforded two porous metal organic frameworks [Cd(bpydc)2(DMF)2·2DMF]n (JMS-3) and [Zn(bpydc)(DMF)·DMF]n (JMS-4). X-ray diffraction studies revealed that both JMS-3...
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Frontiers Media S.A.
2021
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2020.581226/full http://hdl.handle.net/11408/4131 |
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| author | Tshuma, Piwai Makhubela, Banothile C. E. Ndamyabera, Christophe A. Bourne, Susan A. Mehlana, Gift |
| author_facet | Tshuma, Piwai Makhubela, Banothile C. E. Ndamyabera, Christophe A. Bourne, Susan A. Mehlana, Gift |
| author_sort | Tshuma, Piwai |
| collection | DSpace |
| description | The reaction of Cd(NO3)2·4H2O and Zn(NO3)2·6H2O with the bipyridyl dicarboxylate ligand H2bpydc (2,2′-bipyridine-4,4′-dicarboxylic acid) afforded two porous metal organic frameworks [Cd(bpydc)2(DMF)2·2DMF]n (JMS-3) and [Zn(bpydc)(DMF)·DMF]n (JMS-4). X-ray diffraction studies revealed that both JMS-3 and JMS-4 crystallize in the monoclinic crystal. The MOFs possess 2D interdigited networks with (sql) topology. Sorption studies showed that the activated phase of JMS-3 had CO2 volumetric uptakes of 26.50 and 30.89 cm3 (STP) g−1 (1.18 and 1.39 mmol g−1) whist JMS-4 gave 10.96 and 16.08 cm3 (STP) g−1 (0.49 and 0.71 mmol g−1) at 298 and 273 K respectively. |
| format | Article |
| id | ir-11408-4131 |
| institution | My University |
| language | English |
| publishDate | 2021 |
| publisher | Frontiers Media S.A. |
| record_format | dspace |
| spelling | ir-11408-41312022-06-27T13:49:06Z Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen Tshuma, Piwai Makhubela, Banothile C. E. Ndamyabera, Christophe A. Bourne, Susan A. Mehlana, Gift carbon dioxide topology, metal-organic framework adsorption, catalysis The reaction of Cd(NO3)2·4H2O and Zn(NO3)2·6H2O with the bipyridyl dicarboxylate ligand H2bpydc (2,2′-bipyridine-4,4′-dicarboxylic acid) afforded two porous metal organic frameworks [Cd(bpydc)2(DMF)2·2DMF]n (JMS-3) and [Zn(bpydc)(DMF)·DMF]n (JMS-4). X-ray diffraction studies revealed that both JMS-3 and JMS-4 crystallize in the monoclinic crystal. The MOFs possess 2D interdigited networks with (sql) topology. Sorption studies showed that the activated phase of JMS-3 had CO2 volumetric uptakes of 26.50 and 30.89 cm3 (STP) g−1 (1.18 and 1.39 mmol g−1) whist JMS-4 gave 10.96 and 16.08 cm3 (STP) g−1 (0.49 and 0.71 mmol g−1) at 298 and 273 K respectively. 2021-05-07T12:23:56Z 2021-05-07T12:23:56Z 2020-11-05 Article 22962646 https://www.frontiersin.org/articles/10.3389/fchem.2020.581226/full http://hdl.handle.net/11408/4131 en Frontiers In Chemistry Volume 8 | Article 581226; open Frontiers Media S.A. |
| spellingShingle | carbon dioxide topology, metal-organic framework adsorption, catalysis Tshuma, Piwai Makhubela, Banothile C. E. Ndamyabera, Christophe A. Bourne, Susan A. Mehlana, Gift Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen |
| title | Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen |
| title_full | Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen |
| title_fullStr | Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen |
| title_full_unstemmed | Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen |
| title_short | Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen |
| title_sort | synthesis and characterization of 2d metal-organic frameworks for adsorption of carbon dioxide and hydrogen |
| topic | carbon dioxide topology, metal-organic framework adsorption, catalysis |
| url | https://www.frontiersin.org/articles/10.3389/fchem.2020.581226/full http://hdl.handle.net/11408/4131 |
| work_keys_str_mv | AT tshumapiwai synthesisandcharacterizationof2dmetalorganicframeworksforadsorptionofcarbondioxideandhydrogen AT makhubelabanothilece synthesisandcharacterizationof2dmetalorganicframeworksforadsorptionofcarbondioxideandhydrogen AT ndamyaberachristophea synthesisandcharacterizationof2dmetalorganicframeworksforadsorptionofcarbondioxideandhydrogen AT bournesusana synthesisandcharacterizationof2dmetalorganicframeworksforadsorptionofcarbondioxideandhydrogen AT mehlanagift synthesisandcharacterizationof2dmetalorganicframeworksforadsorptionofcarbondioxideandhydrogen |