Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands
Coordination polymers of [Zn(INA)2] (1) (INA = isonicotinate), [Cu2(mal)2(H2O)2(bipy)] (2) (mal = malonate, bipy = 4,4-bipyridine), and [Zn2(OAC)4(bipy)2] (3) (OAC = acetate) were prepared using mechanochemical grinding and heating methods. The materials were characterized with elemental analysis, F...
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2017
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| Online Access: | http://onlinelibrary.wiley.com/doi/10.1002/zaac.201600460/full http://hdl.handle.net/11408/2936 |
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| author | Tella, Adedibu C. Mehlana, Gift Alimi, Lukman O. Bourne, Susan A. |
| author_facet | Tella, Adedibu C. Mehlana, Gift Alimi, Lukman O. Bourne, Susan A. |
| author_sort | Tella, Adedibu C. |
| collection | DSpace |
| description | Coordination polymers of [Zn(INA)2] (1) (INA = isonicotinate), [Cu2(mal)2(H2O)2(bipy)] (2) (mal = malonate, bipy = 4,4-bipyridine), and [Zn2(OAC)4(bipy)2] (3) (OAC = acetate) were prepared using mechanochemical grinding and heating methods. The materials were characterized with elemental analysis, FT-IR spectroscopy, TGA, SEM, EI-MS, BET, and PXRD. Comparison of PXRD patterns of the materials with patterns simulated from single-crystal X-ray diffraction data allowed identification of the products. Compared to conventional synthetic techniques such as solvothermal/hydrothermal solvent-based methods, solvent-free method was found to be simple, highly efficient, and environmentally friendly especially for the preparation of these coordination polymers on a large scale. Solvent-vapor interaction properties of 1, 2, and 3 were investigated by exposure of the compounds to water and methanol at room temperature. |
| format | Article |
| id | ir-11408-2936 |
| institution | My University |
| language | English |
| publishDate | 2017 |
| publisher | Wiley |
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| spelling | ir-11408-29362022-06-27T13:49:06Z Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands Tella, Adedibu C. Mehlana, Gift Alimi, Lukman O. Bourne, Susan A. Solvent-free synthesis Coordination polymers of [Zn(INA)2] (1) (INA = isonicotinate), [Cu2(mal)2(H2O)2(bipy)] (2) (mal = malonate, bipy = 4,4-bipyridine), and [Zn2(OAC)4(bipy)2] (3) (OAC = acetate) were prepared using mechanochemical grinding and heating methods. The materials were characterized with elemental analysis, FT-IR spectroscopy, TGA, SEM, EI-MS, BET, and PXRD. Comparison of PXRD patterns of the materials with patterns simulated from single-crystal X-ray diffraction data allowed identification of the products. Compared to conventional synthetic techniques such as solvothermal/hydrothermal solvent-based methods, solvent-free method was found to be simple, highly efficient, and environmentally friendly especially for the preparation of these coordination polymers on a large scale. Solvent-vapor interaction properties of 1, 2, and 3 were investigated by exposure of the compounds to water and methanol at room temperature. 2017-11-02T17:48:28Z 2017-11-02T17:48:28Z 2017 Article http://onlinelibrary.wiley.com/doi/10.1002/zaac.201600460/full http://hdl.handle.net/11408/2936 en Zeitschrift für anorganische und allgemeine Chemie;Vol. 643, No. 8; p. 523-530 open Wiley |
| spellingShingle | Solvent-free synthesis Tella, Adedibu C. Mehlana, Gift Alimi, Lukman O. Bourne, Susan A. Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands |
| title | Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands |
| title_full | Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands |
| title_fullStr | Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands |
| title_full_unstemmed | Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands |
| title_short | Solvent‐free Synthesis, Characterization and Solvent‐Vapor Interaction of Zinc (II) and Copper (II) Coordination Polymers containing Nitrogen‐donor Ligands |
| title_sort | solvent‐free synthesis, characterization and solvent‐vapor interaction of zinc (ii) and copper (ii) coordination polymers containing nitrogen‐donor ligands |
| topic | Solvent-free synthesis |
| url | http://onlinelibrary.wiley.com/doi/10.1002/zaac.201600460/full http://hdl.handle.net/11408/2936 |
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