Alcohol responsive 2D coordination network of 3-(4-pyridyl)benzoate and Zinc(II)
The solvothermal reaction of 3-(4-pyridyl)benzoic acid and zinc nitrate yielded a 2D network with an sql topology. Both elemental analysis and single crystal X-ray diffraction studies confirmed the formula of the compound as {[Zn(34pba)2] · (0.5 DMF) · (0.5 H2O)}n (1). At room temperature, the desol...
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Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Oldenbourg Wissenschaftsverlag
2016
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Subjects: | |
Online Access: | https://www.degruyter.com/view/j/zkri.2013.228.issue-7/zkri.2013.1607/zkri.2013.1607.xml https://www.researchgate.net/publication/245542421 http://hdl.handle.net/11408/1869 |
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Summary: | The solvothermal reaction of 3-(4-pyridyl)benzoic acid and zinc nitrate yielded a 2D network with an sql topology. Both elemental analysis and single crystal X-ray diffraction studies confirmed the formula of the compound as {[Zn(34pba)2] · (0.5 DMF) · (0.5 H2O)}n (1). At room temperature, the desolvated phase of 1, 1d, absorbs methanol, ethanol, 1-propanol and 1-butanol but not water vapour. |
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