Reversible guest removal and selective guest exchange with a covalent dinuclear wheel-and-axle metallorganic host constituted by half-sandwich Ru(II) wheels connected by a linear diphosphine axle
The organometallic unit {[(p-cymene)RuCl2]2[4,4′-bis(diphenylphosphino)biphenylene]} has been revealed to be a good building block for the construction of wheel-and-axle (waa) crystalline scaffolds able to incorporate different organic solvents. In fact, the synthesis carried out in tetrahydrofuran...
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| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society
2016
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| Subjects: | |
| Online Access: | http://pubs.acs.org/doi/abs/10.1021/acs.cgd.5b00059 http://hdl.handle.net/11408/1868 |
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