Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum)
New divalent transition metal nicotinamide (nia) complexes containing fumarate (fum) dianion and fumaric acid (H2fum), [M(H2O)4(nia)2](fum)·(H2fum) [M = Co (1), Cu (2) and Ni (3)] have been synthesized. The compounds were characterized by elemental analyses, IR, UV-vis, XRPD and TGA. Structural anal...
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| Language: | English |
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Taylor & Francis
2016
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| Online Access: | http://dx.doi.org/10.1080/15533174.2016.1212234 http://hdl.handle.net/11408/1865 |
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| author | Tella, Adedibu C. Owalude, Samson O. Mehlana, Gift Olatunji, Sunday J. Adetitun, David O. Kolawole, Mathew O. Simon, Nzikahyel Alimi, Lukman O. |
| author_facet | Tella, Adedibu C. Owalude, Samson O. Mehlana, Gift Olatunji, Sunday J. Adetitun, David O. Kolawole, Mathew O. Simon, Nzikahyel Alimi, Lukman O. |
| author_sort | Tella, Adedibu C. |
| collection | DSpace |
| description | New divalent transition metal nicotinamide (nia) complexes containing fumarate (fum) dianion and fumaric acid (H2fum), [M(H2O)4(nia)2](fum)·(H2fum) [M = Co (1), Cu (2) and Ni (3)] have been synthesized. The compounds were characterized by elemental analyses, IR, UV-vis, XRPD and TGA. Structural analysis of 3 using single crystal X-ray diffraction technique revealed that the Ni(II) ion is coordinated by four aqua and two nicotinamide ligands in an octahedral geometry. The structure of 3 is completed with fumarate (fum²⁻) dianion acting as counter-ion while fumaric acid (H2fum) is present as a molecule of solvation. The three complexes were investigated for biological activities. |
| format | Article |
| id | ir-11408-1865 |
| institution | My University |
| language | English |
| publishDate | 2016 |
| publisher | Taylor & Francis |
| record_format | dspace |
| spelling | ir-11408-18652022-06-27T13:49:06Z Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum) Tella, Adedibu C. Owalude, Samson O. Mehlana, Gift Olatunji, Sunday J. Adetitun, David O. Kolawole, Mathew O. Simon, Nzikahyel Alimi, Lukman O. Fumarate complexes, nicotinamide, crystal structure, XRPD analysis, biological activity New divalent transition metal nicotinamide (nia) complexes containing fumarate (fum) dianion and fumaric acid (H2fum), [M(H2O)4(nia)2](fum)·(H2fum) [M = Co (1), Cu (2) and Ni (3)] have been synthesized. The compounds were characterized by elemental analyses, IR, UV-vis, XRPD and TGA. Structural analysis of 3 using single crystal X-ray diffraction technique revealed that the Ni(II) ion is coordinated by four aqua and two nicotinamide ligands in an octahedral geometry. The structure of 3 is completed with fumarate (fum²⁻) dianion acting as counter-ion while fumaric acid (H2fum) is present as a molecule of solvation. The three complexes were investigated for biological activities. 2016-11-28T14:01:53Z 2016-11-28T14:01:53Z 2016 Article 1553-3174 http://dx.doi.org/10.1080/15533174.2016.1212234 http://hdl.handle.net/11408/1865 en Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry; open Taylor & Francis |
| spellingShingle | Fumarate complexes, nicotinamide, crystal structure, XRPD analysis, biological activity Tella, Adedibu C. Owalude, Samson O. Mehlana, Gift Olatunji, Sunday J. Adetitun, David O. Kolawole, Mathew O. Simon, Nzikahyel Alimi, Lukman O. Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum) |
| title | Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum) |
| title_full | Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum) |
| title_fullStr | Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum) |
| title_full_unstemmed | Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum) |
| title_short | Synthesis, thermal properties and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [Ni(H 2 O) 4 (nia) 2 ](fum)·(H 2 fum) |
| title_sort | synthesis, thermal properties and biological study of metal(ii) nicotinamide complexes containing fumarate dianion and fumaric acid: crystal structure of [ni(h 2 o) 4 (nia) 2 ](fum)·(h 2 fum) |
| topic | Fumarate complexes, nicotinamide, crystal structure, XRPD analysis, biological activity |
| url | http://dx.doi.org/10.1080/15533174.2016.1212234 http://hdl.handle.net/11408/1865 |
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