The role of C–H⋯π interactions in modulating the breathing amplitude of a 2D square lattice net: alcohol sorption studies
A breathing 2D net 1 {[Zn(34pba)2]•DMF}n assembled from mononuclear zinc (II) centres and 3-(4-pyridyl) benzoate (34pba) ditopic linker is presented. 1 undergoes a displacive phase transition to give 1d, [Zn(34pba)2]n on evacuation of DMF. This is accompanied by a 37% decrease in solvent accessible...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2016
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| Subjects: | |
| Online Access: | http://pubs.rsc.org/en/content/articlepdf/2014/ce/c4ce00496e http://hdl.handle.net/11408/1864 |
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