Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus)

The ability to convert a waste by-product, sunflower seed husk (Helianthus annuus), into an economically cheap adsorbent has been investigated for nitrate removal from aqueous solution through sorption studies. The sunflower seed husk was characterized by physisorption, Brunauer Emmet Teller (BET)....

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Main Authors: Moyo, Mambo, Maringe, A., Chigondo, Fidelis, Nyamunda, Benias C., Shumba, Munyaradzi
Format: Article
Language:English
Published: 2016
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Online Access:https://www.researchgate.net/publication/260613923
http://hdl.handle.net/11408/1535
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author Moyo, Mambo
Maringe, A.
Chigondo, Fidelis
Nyamunda, Benias C.
Shumba, Munyaradzi
author_facet Moyo, Mambo
Maringe, A.
Chigondo, Fidelis
Nyamunda, Benias C.
Shumba, Munyaradzi
author_sort Moyo, Mambo
collection DSpace
description The ability to convert a waste by-product, sunflower seed husk (Helianthus annuus), into an economically cheap adsorbent has been investigated for nitrate removal from aqueous solution through sorption studies. The sunflower seed husk was characterized by physisorption, Brunauer Emmet Teller (BET). Fourier transform Infrared (FTIR) were recorded before and after adsorption to explore the number and position of the functional groups available for nitrate binding on to the studied adsorbent. Optimum adsorption conditions for nitrate removal were determined as a function of pH, adsorbent dosage and contact time. The sorption capacity decreased with increasing sorbent dosage. The optimum contact time was 120 min, optimum biomass dose was 3.0 g and the optimum pH for nitrate removal was 2.0. The adsorption data conformed to both the Langmuir and the Freundlich isotherms but fitted best into the Langmuir model. The R 2 for Langmuir equation was 0.9940 and that for Freundlich was 0.8190. The study demonstrated the efficacy of disposed sunflower seed husk as efficient adsorbent material for the removal of nitrate ions from aqueous solution.
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spelling ir-11408-15352022-06-27T13:49:06Z Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus) Moyo, Mambo Maringe, A. Chigondo, Fidelis Nyamunda, Benias C. Shumba, Munyaradzi Biosorption, sunflower seed husk, BET, FT-IR, equilibrium isotherms The ability to convert a waste by-product, sunflower seed husk (Helianthus annuus), into an economically cheap adsorbent has been investigated for nitrate removal from aqueous solution through sorption studies. The sunflower seed husk was characterized by physisorption, Brunauer Emmet Teller (BET). Fourier transform Infrared (FTIR) were recorded before and after adsorption to explore the number and position of the functional groups available for nitrate binding on to the studied adsorbent. Optimum adsorption conditions for nitrate removal were determined as a function of pH, adsorbent dosage and contact time. The sorption capacity decreased with increasing sorbent dosage. The optimum contact time was 120 min, optimum biomass dose was 3.0 g and the optimum pH for nitrate removal was 2.0. The adsorption data conformed to both the Langmuir and the Freundlich isotherms but fitted best into the Langmuir model. The R 2 for Langmuir equation was 0.9940 and that for Freundlich was 0.8190. The study demonstrated the efficacy of disposed sunflower seed husk as efficient adsorbent material for the removal of nitrate ions from aqueous solution. 2016-06-09T09:24:33Z 2016-06-09T09:24:33Z 2012 Article 2229-5216 https://www.researchgate.net/publication/260613923 http://hdl.handle.net/11408/1535 en International Journal of Advances in Science and Technology;Vol. 5, No.6; p. 47-66 open
spellingShingle Biosorption, sunflower seed husk, BET, FT-IR, equilibrium isotherms
Moyo, Mambo
Maringe, A.
Chigondo, Fidelis
Nyamunda, Benias C.
Shumba, Munyaradzi
Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus)
title Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus)
title_full Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus)
title_fullStr Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus)
title_full_unstemmed Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus)
title_short Adsorptive removal of nitrate Ions from aqueous solutions using acid treated sunflower seed husk (Helianthus annuus)
title_sort adsorptive removal of nitrate ions from aqueous solutions using acid treated sunflower seed husk (helianthus annuus)
topic Biosorption, sunflower seed husk, BET, FT-IR, equilibrium isotherms
url https://www.researchgate.net/publication/260613923
http://hdl.handle.net/11408/1535
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AT chigondofidelis adsorptiveremovalofnitrateionsfromaqueoussolutionsusingacidtreatedsunflowerseedhuskhelianthusannuus
AT nyamundabeniasc adsorptiveremovalofnitrateionsfromaqueoussolutionsusingacidtreatedsunflowerseedhuskhelianthusannuus
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