Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP)

Rooibos (Aspalathus linearis) plants are cultivated for the production of the Rooibos tea. In this work, biosorption process of Pb(II) from aqueous solution on Rooibos shoot powder (RSP) was studied in a batch process. The effect of experimental parameters such as solution pH (2-9), contact time (30...

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Main Authors: Kanu, Sheku Alfred, Moyo, Mambo, Zvinowanda, Caliphs, Okonkwo, Jonathan
Format: Article
Language:English
Published: Taylor & Francis 2016
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Online Access:http://hdl.handle.net/11408/1202
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author Kanu, Sheku Alfred
Moyo, Mambo
Zvinowanda, Caliphs
Okonkwo, Jonathan
author_facet Kanu, Sheku Alfred
Moyo, Mambo
Zvinowanda, Caliphs
Okonkwo, Jonathan
author_sort Kanu, Sheku Alfred
collection DSpace
description Rooibos (Aspalathus linearis) plants are cultivated for the production of the Rooibos tea. In this work, biosorption process of Pb(II) from aqueous solution on Rooibos shoot powder (RSP) was studied in a batch process. The effect of experimental parameters such as solution pH (2-9), contact time (30-180 min) and initial Pb(II) concentration (25-400 mg L-1), adsorbent dosage (0.2-2.1 g), and temperature (25-80 ”C) on biosorption process was examined. In an attempt to determine the biosorption capacity and rate of Pb(II) removal, isotherm and kinetic data were modeled using different equations. To this end, the biosorption process by RSP followed the Langmuir model for Pb(II) ions (R2 = 0.9907), with maximum monolayer adsorption capacity of 18.90 mg g-1. Kinetic data were properly fitted with the pseudo-second order kinetic model, and it can be seen that the calculated cjf (cal) value (11.31 mg g-1) agrees with the experimental value (12.80 mg g-1). Furthermore, the biosorbent showed good removal of Pb(II) from industrial wastewaters.
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spelling ir-11408-12022022-06-27T13:49:06Z Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP) Kanu, Sheku Alfred Moyo, Mambo Zvinowanda, Caliphs Okonkwo, Jonathan Biosorption; rooibos shoot powder; isotherm; kinetics; wastewater Rooibos (Aspalathus linearis) plants are cultivated for the production of the Rooibos tea. In this work, biosorption process of Pb(II) from aqueous solution on Rooibos shoot powder (RSP) was studied in a batch process. The effect of experimental parameters such as solution pH (2-9), contact time (30-180 min) and initial Pb(II) concentration (25-400 mg L-1), adsorbent dosage (0.2-2.1 g), and temperature (25-80 ”C) on biosorption process was examined. In an attempt to determine the biosorption capacity and rate of Pb(II) removal, isotherm and kinetic data were modeled using different equations. To this end, the biosorption process by RSP followed the Langmuir model for Pb(II) ions (R2 = 0.9907), with maximum monolayer adsorption capacity of 18.90 mg g-1. Kinetic data were properly fitted with the pseudo-second order kinetic model, and it can be seen that the calculated cjf (cal) value (11.31 mg g-1) agrees with the experimental value (12.80 mg g-1). Furthermore, the biosorbent showed good removal of Pb(II) from industrial wastewaters. 2016-05-04T13:34:41Z 2016-05-04T13:34:41Z 2015 Article 1944-3994 http://hdl.handle.net/11408/1202 en Desalination and Water Treatment;p1-9. open Taylor & Francis
spellingShingle Biosorption; rooibos shoot powder; isotherm; kinetics; wastewater
Kanu, Sheku Alfred
Moyo, Mambo
Zvinowanda, Caliphs
Okonkwo, Jonathan
Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP)
title Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP)
title_full Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP)
title_fullStr Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP)
title_full_unstemmed Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP)
title_short Biosorption of Pb(II) from aqueous solution using Rooibos shoot powder (RSP)
title_sort biosorption of pb(ii) from aqueous solution using rooibos shoot powder (rsp)
topic Biosorption; rooibos shoot powder; isotherm; kinetics; wastewater
url http://hdl.handle.net/11408/1202
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